Nevertheless, resistance to immersion in boiling water is used as a test for grading plywood; see here.
It’s not that unusual to use short exposures to more extreme conditions than would be encountered in actual use as an index for performance over longer periods under more reasonable conditions. It’s impractical to test each lot of plywood by exposing it to actual weather for 5 years, but the ability to withstand a few hours of boiling offers some indication of its resistance to heat and moisture.
Given that some of the other tests involve immersion in water without boiling, and that, as I said, water treatment is more readily incorporated into a standard test than weather exposure, I would expect “Water and Boil Proof” to be the original source of the acronym, with “Weather...” a later substitution based on the fact that passing the water-and-boil test would provide a reasonable expectation of weather-resistance.